Verified Solution • 2025–26 Session moderate

QJEEM03Chbac4: JEE Main 2003 Chemistry - Class 12 JEEM03Chbac4 Solution: A red solid is insolvable in water. However it becomes soluble…

A red solid is insolvable in water. However it becomes soluble if some KI is added to water. Heating the red solid in a test tube results in liberation of some violet colored fumes and droplets of a metal appear on the cooler parts of the test tube. The red solid is :

Multiple Choice Options

  • A HgI2
  • B HgO
  • C Pb3O4
  • D (NH4)2Cr2O7

Step-by-Step Verified Solution

When KI is added to mercuric iodide it dissolve in it and form complex.

HgI2red,solid(insoluble)+KI→K2[HgI4](soluble)

On heating HgI2 decomposes as

HgI2Hg⇌+I2(violetvapours)

Related Learning Resources & Exam Preparation