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QJEEM03Ch4c5d: JEE Main 2003 Chemistry - Class 11 JEEM03Ch4c5d Solution: In the anion HCOO the two carbon-oxygen bonds are found to be…

In the anion HCOO −- the two carbon-oxygen bonds are found to be of equal length. What is the reason for it?

Multiple Choice Options

  • A The C = O bond is weaker than the C-O bond
  • B The anion HCOO- has two resonating structures
  • C The anion is obtained by removal of a proton from the acid molecule
  • D Electronic orbitals of carbon atom are hybridised

Step-by-Step Verified Solution

The anion is

AIEEE 2003 Chemistry - Basics of Organic Chemistry Question 249 English Explanation 1

HCOO−HCO{O^ - } exists in following resonating structures

AIEEE 2003 Chemistry - Basics of Organic Chemistry Question 249 English Explanation 2

And actual structure will be,

AIEEE 2003 Chemistry - Basics of Organic Chemistry Question 249 English Explanation 3

Bond order of this anion = 32{3 \over 2} = 1.5.

As 1.5 is exactly in the middle of 1 and 2 so, the bond length will be equal between all carbon and oxygen atom.

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