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QJEEAdv24Ch6ffc: JEE Advanced 2024 Chemistry - Class 12 JEEAdv24Ch6ffc Solution: Among the following options, select the option in which each…

Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other.

 [en =H2NCH2CH2NH2 ] \text { [en }=\mathrm{H}_2 \mathrm{NCH}_2 \mathrm{CH}_2 \mathrm{NH}_2 \text { ] }

Multiple Choice Options

  • A Set-I: [Ni(CO)4]\left[\mathrm{Ni}(\mathrm{CO})_4\right] and [PdCl2(PPh3)2]\left[\mathrm{PdCl}_2\left(\mathrm{PPh}_3\right)_2\right] Set-II: [Co(NH3)5Cl]SO4\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4 and [Co(NH3)5(SO4)]Cl\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Cl}
  • B Set-I: [Co(en)(NH3)2Cl2]\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right] and [PdCl2(PPh3)2]\left[\mathrm{PdCl}_2\left(\mathrm{PPh}_3\right)_2\right] Set-II: [Co(NH3)6][Cr(CN)6]\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right] and [Cr(NH3)6][Co(CN)6]\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Co}(\mathrm{CN})_6\right]
  • C Set-I: [Co(NH3)3(NO2)3]\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right] and [Co(en)2Cl2]\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right] Set-II: [Co(NH3)5Cl]SO4\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4 and [Co(NH3)5(SO4)]Cl\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Cl}
  • D Set-I: [Cr(NH3)5Cl]Cl2\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2 and [Co(en)(NH3)2Cl2]\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right] Set-II: [Cr(H2O)6]Cl3\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3 and [Cr(H2O)5Cl]Cl2⋅H2O\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2 \cdot \mathrm{H}_2 \mathrm{O}

Step-by-Step Verified Solution

JEE Advanced 2024 Paper 1 Online Chemistry - Coordination Compounds Question 5 English Explanation 1 JEE Advanced 2024 Paper 1 Online Chemistry - Coordination Compounds Question 5 English Explanation 2

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