Verified Solution • 2025–26 Session very hard

QJEEA-2024-08: JEE Advanced 2024 JEEA-2024-08 Solution: Q.8 The specific heat capacity of a substance is temperature…

Q.8 The specific heat capacity of a substance is temperature dependent and is given by the formula

𝐶 = 𝑘𝑇, where 𝑘 is a constant of suitable dimensions in SI units, and 𝑇 is the absolute temperature. If the heat required to raise the temperature of 1 kg of the substance from −73 °C to 27 °C is 𝑛𝑘, the value of 𝑛 is    .

 

[Given: 0 K = −273 °C.]

Step-by-Step Verified Solution

Solution: 2500

  1. Convert Temperatures to Kelvin:
  • T₁ = -73 °C = -73 + 273 K = 200 K
  • T₂ = 27 °C = 27 + 273 K = 300 K
  1. Heat Required (dQ):
  • dQ = mC dT, where m is the mass, C is the specific heat capacity, and dT is the change in temperature.
  • Given C = kT, we have dQ = m(kT) dT.
  1. Integrate to Find Total Heat (Q):
  • Q = ∫dQ = ∫m(kT) dT
  • Q = m k ∫T dT (from T₁ to T₂)
  • Q = mk [T²/2] (from 200 K to 300 K)
  • Q = mk [(300² / 2) - (200² / 2)]
  • Q = mk [(90000 / 2) - (40000 / 2)]
  • Q = mk [(90000 - 40000) / 2]
  • Q = mk [50000 / 2]
  • Q = mk (25000)
  1. Given Mass (m):
  • m = 1 kg
  • Q = 1 * k * 25000 = 25000k
  1. Compare with nk:
  • Q = nk
  • 25000k = nk
  • n = 25000

Answer:

The value of n is 25000.

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