Verified Solution • 2025–26 Session moderate

QJEEAdv23Ch7c9f: JEE Advanced 2023 Chemistry - Class 11 JEEAdv23Ch7c9f Solution:  The value of enthalpy change,  H β − H α…

 The value of enthalpy change, Hβ−Hα (in Jmol−1 ), at 300 K is  ________.

Step-by-Step Verified Solution

As the phase transition temperature is 600 K600 \mathrm{~K}

So at 600 KΔGrxn∘=0600 \mathrm{~K} \quad \Delta \mathrm{G}_{\mathrm{rxn}}^{\circ}=0 So ΔH∘reaction (600) =TΔS∘reaction (600) \Delta \mathrm{H}^{\circ}{ }_{\text {reaction (600) }}=\mathrm{T} \Delta \mathrm{S}^{\circ}{ }_{\text {reaction (600) }}

ΔH∘(600)=600×1=600Joule/mole\Delta \mathrm{H}^{\circ}{ }_{(600)}=600 \times 1=600 \mathrm{Joule} / \mathrm{mole}

So ΔH600−ΔH300=ΔCP(T2−T1)\Delta \mathrm{H}_{600}-\Delta \mathrm{H}_{300}=\Delta \mathrm{C}_{\mathrm{P}}\left(\mathrm{T}_2-\mathrm{T}_1\right)

ΔH600−ΔH300=1×300\Delta \mathrm{H}_{600}-\Delta \mathrm{H}_{300}=1 \times 300

ΔH300=ΔH600−300=600−300=300\Delta \mathrm{H}_{300}=\Delta \mathrm{H}_{600}-300=600-300=300 Joule // mole.

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