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QJEEAdv20Ch0235: JEE Advanced 2020 Chemistry - Class 12 JEEAdv20Ch0235 Solution: In the reaction scheme shown below Q, R and S are the major…

In the reaction scheme shown below Q, R and S are the major products.

JEE Advanced 2020 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 53 English

The correct structure of

Multiple Choice Options

  • A S is
  • B R is
  • C S is
  • D Q is

Step-by-Step Verified Solution

Compound (P) undergoes Friedel-Craft acylation reaction in presence of succinic anhydride and AlCl3 to gives an acid (Q).

Compound (Q) on treatment with Zn-Hg/HCl undergoes Clemmensen reduction, where ketone group change into alkane and on further reaction with dehydrating agent H3PO4 gives compound (R).

Compound (R) on reaction with Grignard reagent and heated in presence of acid gives dehydrating product (S).

JEE Advanced 2020 Paper 1 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 53 English Explanation

Thus, the option (b) and (d) are correct.

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