QJEEAdv19Ch2347: JEE Advanced 2019 Chemistry - Class 12 JEEAdv19Ch2347 Solution: With reference to aqua-regia, choose the correct option(s).
With reference to aqua-regia, choose the correct option(s).
Multiple Choice Options
AAqua-regia is prepared by mixing conc. HCl and conc. HNO3 in 3 : 1 (v / v) ratio
BThe yellow colour of aqua-regia is due to the presence of NOCl and Cl2
CReaction of gold with aqua-regia produces an anion having Au in +3 oxidation state
DReaction of gold with aqua regia produces NO2 in the absence of air
Step-by-Step Verified Solution
The explanation of given statements are as follows :
(a) Aqua-regia is prepared by mixing conc. HCl and conc. HNO3 in 3 : 1 (v/v) ratio and is used in oxidation of gold and platinum. Hence, option (a) is correct.
(b) Yellow colour of aqua-regia is due to its decomposition into NOCl (orange yellow) and Cl2 (greenish yellow). Hence, option (b) is correct.
(c) When gold reacts with aqua-regia then it produces anion complex in which Au has +3 oxidation state.
Hence, option (c) is correct.
(d) Reaction of gold with aqua-regia produces NO gas in absence of air. Hence, option (d) is incorrect.