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QJEEAdv19Ch2347: JEE Advanced 2019 Chemistry - Class 12 JEEAdv19Ch2347 Solution: With reference to aqua-regia, choose the correct option(s).

With reference to aqua-regia, choose the correct option(s).

Multiple Choice Options

  • A Aqua-regia is prepared by mixing conc. HCl and conc. HNO3 in 3 : 1 (v / v) ratio
  • B The yellow colour of aqua-regia is due to the presence of NOCl and Cl2
  • C Reaction of gold with aqua-regia produces an anion having Au in +3 oxidation state
  • D Reaction of gold with aqua regia produces NO2 in the absence of air

Step-by-Step Verified Solution

The explanation of given statements are as follows :

(a) Aqua-regia is prepared by mixing conc. HCl and conc. HNO3 in 3 : 1 (v/v) ratio and is used in oxidation of gold and platinum. Hence, option (a) is correct.

(b) Yellow colour of aqua-regia is due to its decomposition into NOCl (orange yellow) and Cl2 (greenish yellow). Hence, option (b) is correct.

(c) When gold reacts with aqua-regia then it produces AuCl4− anion complex in which Au has +3 oxidation state.

JEE Advanced 2019 Paper 2 Offline Chemistry - d and f Block Elements Question 17 English Explanation

Hence, option (c) is correct.

(d) Reaction of gold with aqua-regia produces NO gas in absence of air. Hence, option (d) is incorrect.

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