Verified Solution • 2025–26 Session moderate

QJEEAdv17Chfede: JEE Advanced 2017 Chemistry - Class 12 JEEAdv17Chfede Solution: The product S is

The product S is

Multiple Choice Options

  • A https://ik.imagekit.io/novatra/photos/bff597dde3ebab6dbae81e7b8924fe9aef9fcfa9422751fcc74dce954abced1f.webp
  • B https://ik.imagekit.io/novatra/photos/6e57a709bab03fea1b1d869dc0cf46cd024af07320a37e4dd7bb6dc708af1f44.webp
  • C https://ik.imagekit.io/novatra/photos/246bd86c4327da8b48d160dac5e4f2b313efff159712af8abb1ef861312e8b17.webp
  • D https://ik.imagekit.io/novatra/photos/fdccc9a275634249e47d4125d58cfe0117bb1515d43b6410db0765d8f9892f89.webp

Step-by-Step Verified Solution

(i) Compound P reacts with CH3MgBr\mathrm{CH}_3 \mathrm{MgBr} in excess in (C2H5)2O\left(\mathrm{C}_2 \mathrm{H}_5\right)_2 \mathrm{O} followed by addition of water to form alcohol derivative of the compound.

JEE Advanced 2017 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 59 English Explanation 1
(ii) Compound QQ undergoes dehydration in presence of H2SO4\mathrm{H}_2 \mathrm{SO}_4 at 0∘C0^{\circ} \mathrm{C} .

JEE Advanced 2017 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 59 English Explanation 2
(iii) Compound RR undergoes acylation of aromatic ring in presence of JEE Advanced 2017 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 59 English Explanation 3 and anhydrous AlCl3\mathrm{AlCl}_3 .

JEE Advanced 2017 Paper 2 Offline Chemistry - Aldehydes, Ketones and Carboxylic Acids Question 59 English Explanation 4
The substitution should take place at ortho or para position but due to steric crowding at ortho and occupancy of para position. Meta position is substituted with acetyl group.

Related Learning Resources & Exam Preparation