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QJEEAdv15Ch42b4: JEE Advanced 2015 Chemistry - Class 11 JEEAdv15Ch42b4 Solution: Not considering the electronic spin, the degeneracy of the…

Not considering the electronic spin, the degeneracy of the second excited state( n = 3) of H atom is 9, while the degeneracy of the second excited state of H– is ___________.

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(i) Number of electrons in hydride ion (H−)\left(\mathrm{H}^{-}\right) is =2=2

(ii) Electronic configuration of ground state in H−\mathrm{H}^{-} ion (G.S) = 1s2

JEE Advanced 2015 Paper 1 Offline Chemistry - Structure of Atom Question 15 English Explanation 1

(iii) Electronic configuration of first excited state of H−\mathrm{H}^{-} ion (ES1)\left(\mathrm{E}{S_1}\right)

JEE Advanced 2015 Paper 1 Offline Chemistry - Structure of Atom Question 15 English Explanation 2

(iv) Electronic configuration of second excited state of H−(\mathrm{H}^{-}\left(\right. E.S 2)\left._2\right)

JEE Advanced 2015 Paper 1 Offline Chemistry - Structure of Atom Question 15 English Explanation 3

(v) The electron in 2p2 p orbital can occupy any three 2p2 p orbitals 2px′2py2 p_{x^{\prime}} 2 p_y and 2pz2 p_z as follows :

JEE Advanced 2015 Paper 1 Offline Chemistry - Structure of Atom Question 15 English Explanation 4

Hence, three degenerate orbitals represents second excited state of H–.

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