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QJEEAdv08Ch8133: JEE Advanced 2008 Chemistry - Class 11 JEEAdv08Ch8133 Solution: The correct stability order for the following species is :

The correct stability order for the following species is :

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English

Multiple Choice Options

  • A (II) > (IV) > (I) > (III)
  • B (I) > (II) > (III) > (IV)
  • C (II) > (I) > (IV) > (III)
  • D (I) > (III) > (II) > (IV)

Step-by-Step Verified Solution

Stability of the following species depends upon the no. of α hydrogen which can undergoes hyperconjugation as well as resonance. Higher the no. of α hydrogen, higher will be the stability of the carbocation.

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English Explanation 1

Stabilizes by resonance and have six α-hydrogen atoms (hyperconjugation).

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English Explanation 2

Stabilizes by resonance and have three α-hydrogen atoms.

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English Explanation 3

It have five α-hydrogen atoms.

IIT-JEE 2008 Paper 2 Offline Chemistry - Basics of Organic Chemistry Question 2 English Explanation 4

It have only two α-hydrogen atoms.

∴ (I) > (III) > (II) > (IV)

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