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QJEEAdv06Chd39f: JEE Advanced 2006 Chemistry - Class 12 JEEAdv06Chd39f Solution: The species present in solution when CO 2 is dissolved in water …

The species present in solution when CO2 is dissolved in water are

Multiple Choice Options

  • A CO2, H2CO3, HCO3−HCO_3^- , CO32−CO_3^{2-}
  • B H2CO3H_2CO_3 , CO32−CO_3^{2-}
  • C CO32−CO_3^{2-} , HCO3−HCO_3^-
  • D CO2, H2CO3

Step-by-Step Verified Solution

When carbon dioxide (CO2) is dissolved in water, it undergoes a series of chemical reactions that result in various species being present in the solution. The reactions can be described as follows:

1. Carbon dioxide reacts with water to form carbonic acid:

CO2+H2O⇌H2CO3CO_2 + H_2O \rightleftharpoons H_2CO_3

2. Carbonic acid can dissociate into a bicarbonate ion and a proton:

H2CO3⇌HCO3−+H+H_2CO_3 \rightleftharpoons HCO_3^- + H^+

3. Bicarbonate ion can further dissociate into a carbonate ion and a proton:

HCO3−⇌CO32−+H+HCO_3^- \rightleftharpoons CO_3^{2-} + H^+

Based on these reactions, the species present in the solution when CO2 is dissolved in water include CO2, H2CO3H_2CO_3 , HCO3−HCO_3^- , and CO32−CO_3^{2-} . Thus, the correct option is:

Option A: CO2, H2CO3, HCO3−HCO_3^- , CO32−CO_3^{2-}

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