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QJEEAdv03Cha41e: JEE Advanced 2003 Chemistry - Class 12 JEEAdv03Cha41e Solution: 1 gm of charcoal adsorbs 100 ml 0.5 M CH 3 COOH to form a…

1 gm of charcoal adsorbs 100 ml 0.5 M CH3COOH to form a monolayer, and thereby the molarity of CH3COOH reduces to 0.49. Calculate the surface area of the charcoal adsorbed by each molecule of acetic acid. Surface area of charcoal = 3.01 × 102 m2/gm.

Step-by-Step Verified Solution

The number of moles of acetic acid in 100 mL (before adding charcoal) = 0.05 mol

The number of moles of acetic acid in 100 mL (after adding charcoal) = 0.049 mol

The number of moles of acetic acid adsorbed on the surface of charcoal = 0.05 - 0.049 = 0.001 mol

The number of molecules of acetic acid adsorbed on the surface of charcoal = 0.001 × 6.02 × 1023 = 6.02 × 1020

Given that the surface area of charcoal = 3.01 × 102 m2 , so the area occupied by single acetic acid molecule on the surface of charcoal is

= 3.01×1026.02×1020 = 5 × 10-19 m2

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